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  Dr. Fabio Marchetti
  Assistant Professor (Ricercatore)
  Address : Dipartimento di Chimica e Chimica Industriale
                  Via Risorgimento 35, 56126 Pisa (I)
  Phone : +39 050 2219245
  Fax : +39 050 2219260
  E-Mail : fabmar@dcci.unipi.it | fabio.marchetti1@unipi.it

   
 
 
 
 

Born 1974, Bologna (Italy)
1999 Degree in Industrial Chemistry summa cum laude (University of Bologna)
2003 PhD in Chemistry (University of Bologna)
2006 Permanent researcher (University of Pisa)
Awards: Premio Nasini 2014 (Società Chimica Italiana, Divisione Chimica Inorganica)

 
 
 

  Research Interests and selected publications     

 
Coordination chemistry of high valent transition metal halides and activation of small molecules
  M. Bortoluzzi, E. Ferretti, F. Marchetti, G. Pampaloni, S. Zacchini, "A structurally-characterized NbCl5–NHC   adduct", Chem. Commun., 2014, 50, 4472
  M. Bortoluzzi, F. Marchetti, G. Pampaloni, S. Zacchini, "Tribenzylamine C-H activation and intermolecular hydrogen transfer promoted by WCl6", Inorg. Chem., 2014, 53, 3832
  L. Favero, F. Marchetti, G. Pampaloni, S. Zacchini, "The interaction of molybdenum pentachloride with O- and S-heterocycles", Dalton Trans., 2014, 43, 495
  F. Marchetti, G. Pampaloni, “Interaction of niobium and tantalum pentahalides with O-donors: coordination chemistry and activation reactions [Feature Article]”, Chem. Commun., 2012, 48, 635
 
 
Salts containing unusual organic cations stable at room temperature
  F. Marchetti, G. Pampaloni, C. Pinzino, "Long-lived radical cation salts obtained by interaction of monocyclic arenes with Niobium and Tantalum pentahalides at room temperature: EPR and DFT studies", Chem. Eur. J., 2013, 19, 13962
  F. Marchetti, G. Pampaloni, C. Pinzino, S. Zacchini, "Stable [M2F11]– (M = Nb, Ta) salts of protonated 1,3-dimethoxybenzene", Eur. J. Inorg. Chem., 2013, 33, 5755
  F. Marchetti, G. Pampaloni, C. Pinzino, S. Zacchini, "Long-lived radical cations of monocyclic arenes at room temperature obtained by NbF5 acting as an oxidizing agent and counterion precursor", Angew. Chem. Int. Ed., 2010, 49, 5268
 
 
Synthesis of functionalized organometallic ligands via stereo- and regio-selective reactions at
   diiron/diruthenium centres
  F. Marchetti, S. Zacchini, V. Zanotti, “Coupling of isocyanide and μ-aminocarbyne ligands in diiron complexes promoted by hydride addition”, Organometallics, 2014, 33, 3990
  L. Busetto, F. Marchetti, R. Mazzoni, M. Salmi, S. Zacchini, V. Zanotti, Chem. Commun., 2010, 3327
 
 
Synthesis of transition metal complexes with potential anticancer activity
 
 
 
 
 
 
 
 

 

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